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Question -

The enthalpy of combustion of methane,graphite and dihydrogen at 298 K are, –890.3 kJ mol–1 –393.5 kJ mol–1, and –285.8 kJ mol–1 respectively.Enthalpy of formation of CH4(g) will be

(i) –74.8 kJ mol–1            (ii) –52.27 kJ mol–1

(iii) +74.8 kJ mol–1          (iv) +52.26 kJ mol–1.



Answer -

According to the question,

Thus, the desired equation is the one thatrepresents the formation of CH4 (g) i.e.,

Enthalpy of formation of CH4(g= –74.8 kJ mol–1

Hence,alternative (i) is correct.

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